Worldwide interest in low grade heat valorization using organic Rankine cycle (ORC) technologies has increased significantly. A new small-scale ORC with a net capacity of 3 kW was efficiently integrated with a concentrated solar power technology for electricity generation. The excess heat source from Photovoltaic (PV) collectors with a maximum temperature of 100 °C was utilized through a supercritical heat exchanger that uses R-404A as working medium. By ensuring supercritical heat transfer leads to a better thermal match in the heat exchanger and improved overall cycle efficiency. A helical coil heat exchanger was designed by using heat transfer correlations from the literature. These heat transfer correlations were derived for different conditions than ORCs and their estimated uncertainty is ~20%. In order to account for the heat transfer correlation uncertainties this component was oversized by 20%. Next, a prototype was built and installed in an integrated concentrated photovoltaic/thermal (CPV/T)/Rankine system. The results from the measurements show that for better estimation of the sizing of the heat exchanger a more accurate correlation is required in order to design an optimal configuration and thus employ cheaper components.