LAPSE:2018.1104
Published Article
LAPSE:2018.1104
Analytical Model for Voltage-Dependent Photo and Dark Currents in Bulk Heterojunction Organic Solar Cells
Mesbahus Saleheen, Salman M. Arnab, M. Z. Kabir
November 28, 2018
A physics-based explicit mathematical model for the external voltage-dependent forward dark current in bulk heterojunction (BHJ) organic solar cells is developed by considering Shockley-Read-Hall (SRH) recombination and solving the continuity equations for both electrons and holes. An analytical model for the external voltage-dependent photocurrent in BHJ organic solar cells is also proposed by incorporating exponential photon absorption, dissociation efficiency of bound electron-hole pairs (EHPs), carrier trapping, and carrier drift and diffusion in the photon absorption layer. Modified Braun’s model is used to compute the electric field-dependent dissociation efficiency of the bound EHPs. The overall net current is calculated considering the actual solar spectrum. The mathematical models are verified by comparing the model calculations with various published experimental results. We analyze the effects of the contact properties, blend compositions, charge carrier transport properties (carrier mobility and lifetime), and cell design on the current-voltage characteristics. The power conversion efficiency of BHJ organic solar cells mostly depends on electron transport properties of the acceptor layer. The results of this paper indicate that improvement of charge carrier transport (both mobility and lifetime) and dissociation of bound EHPs in organic blend are critically important to increase the power conversion efficiency of the BHJ solar cells.
Keywords
analytical model, charge collection, current-voltage characteristics, dark current, organic solar cells, trapping/recombination
Suggested Citation
Saleheen M, Arnab SM, Kabir MZ. Analytical Model for Voltage-Dependent Photo and Dark Currents in Bulk Heterojunction Organic Solar Cells. (2018). LAPSE:2018.1104
Author Affiliations
Saleheen M: Department of Electrical and Computer Engineering, Concordia University, 1455 Blvd. de Maisonneuve West, Montreal, QC H3G 1M8, Canada
Arnab SM: Department of Electrical and Computer Engineering, Concordia University, 1455 Blvd. de Maisonneuve West, Montreal, QC H3G 1M8, Canada
Kabir MZ: Department of Electrical and Computer Engineering, Concordia University, 1455 Blvd. de Maisonneuve West, Montreal, QC H3G 1M8, Canada
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Journal Name
Energies
Volume
9
Issue
6
Article Number
E412
Year
2016
Publication Date
2016-05-26
Published Version
ISSN
1996-1073
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PII: en9060412, Publication Type: Journal Article
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LAPSE:2018.1104
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doi:10.3390/en9060412
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Nov 28, 2018
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CC BY 4.0
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[v1] (Original Submission)
Nov 28, 2018
 
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Nov 28, 2018
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Original Submitter
Calvin Tsay
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