LAPSE:2018.0151
Published Article
LAPSE:2018.0151
Modeling of the Copolymerization Kinetics of n-Butyl Acrylate and d-Limonene Using PREDICI ®
July 30, 2018
Kinetic modeling of the bulk copolymerization of d-limonene (Lim) and n-butyl acrylate (BA) at 80 °C was performed using PREDICI®. Model predictions of conversion, copolymer composition and average molecular weights are compared to experimental data at five different feed compositions (BA mol fraction = 0.5 to 0.9). The model illustrates the significant effects of degradative chain transfer due to the allylic structure of Lim as well as the intramolecular chain transfer mechanism due to BA.
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Keywords
d-limonene, Modelling, n-butyl acrylate, polymerization kinetics
Subject
Suggested Citation
Ren S, Vivaldo-Lima E, Dubé MA. Modeling of the Copolymerization Kinetics of n-Butyl Acrylate and d-Limonene Using PREDICI ®. (2018). LAPSE:2018.0151
Author Affiliations
Ren S: Department of Chemical and Biological Engineering, Centre for Catalysis Research and Innovation, University of Ottawa, 161 Louis Pasteur Pvt., Ottawa, ON K1N 6N5, Canada
Vivaldo-Lima E: Facultad de Química, Departamento de Ingeniería Química, Universidad Nacional Autónoma de México, México D.F. 04510, Mexico
Dubé MA: Department of Chemical and Biological Engineering, Centre for Catalysis Research and Innovation, University of Ottawa, 161 Louis Pasteur Pvt., Ottawa, ON K1N 6N5, Canada [ORCID]
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Vivaldo-Lima E: Facultad de Química, Departamento de Ingeniería Química, Universidad Nacional Autónoma de México, México D.F. 04510, Mexico
Dubé MA: Department of Chemical and Biological Engineering, Centre for Catalysis Research and Innovation, University of Ottawa, 161 Louis Pasteur Pvt., Ottawa, ON K1N 6N5, Canada [ORCID]
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Journal Name
Processes
Volume
4
Issue
1
Article Number
E1
Year
2015
Publication Date
2015-12-24
Published Version
ISSN
2227-9717
Version Comments
Fixed incorrect licensing setting. All content is the same.
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PII: pr4010001, Publication Type: Journal Article
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LAPSE:2018.0151
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doi:10.3390/pr4010001
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[v2] (Fixed incorrect licensing setting. All c...)
Jul 30, 2018
[v1] (Original Submission)
Jul 30, 2018
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Jul 30, 2018
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